Anne LESAGE

ISA Deputy Director
work phone: 0426233875

Research

My research interests concern the development and application of advanced solid-state NMR methods to solve challenging problems in chemistry.
In particular, I am pursuing an innovative research line on the demanding structural characterization of surface catalysts by NMR.
I have been recently working on the development of DNP enhanced NMR methods to look at surface species in materials science.

Biography

Anne Lesage received her degree of ‘Ingénieur’ in 1992 from the Ecole Centrale de Paris, France. In parallel, she obtained a Masters degree in Biophysics, at the Institut de Biologie et de Chimie des Protéines (IBCP) in Lyon. She then completed her PhD in the same laboratory, where she worked on the structural characterization of collagen assemblies by solution NMR, under the supervision of Prof. Michel Van Der Rest. In 1994, she accepted a full-time position at the CNRS in the Chemistry Department of the Ecole Normale Supérieure de Lyon (as ‘Ingénieur de Recherche’), where she started to work with Prof. Lyndon Emsley on the development of high-resolution solid-state NMR techniques for spin I = 1/2 nuclei, and their application to the structural characterization of complex solid systems, including surface catalysts and proteins. She obtained her Habilitation Thesis in 2003. Since 2008, she has been working at the High Field NMR Center of Lyon, which is now affiliated to the Institute of Analytical Sciences. Her recent research works concern the development of high-field DNP enhanced solid-state NMR spectroscopy to investigate the structure of complex materials, including surfaces.

Publications

Publications HAL de anne,lesage

2017

Journal articles

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Jasmine Viger-Gravel, Pierrick Berruyer, David Gajan, Jean-Marie Basset, Anne Lesage, et al.. Frozen Acrylamide Gels as Dynamic Nuclear Polarization Matrices. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2017, 56 (30), pp.8726-8730. 〈10.1002/anie.201703758〉. 〈hal-01569574〉
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Arthur C. Pinon, Judith Schlagnitweit, Pierrick Berruyer, Aaron J. Rossini, Moreno Lelli, et al.. Measuring Nano- to Microstructures from Relayed Dynamic Nuclear Polarization NMR. Journal of Physical Chemistry C, American Chemical Society, 2017, 121 (29), pp.15993-16005. 〈10.1021/acs.jpcc.7b04438〉. 〈hal-01576889〉
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Murielle F. Delley, Giuseppe Lapadula, Francisco Nunez-Zarur, Aleix Comas-Vives, Vidmantas Kalendra, et al.. Local Structures and Heterogeneity of Silica-Supported M(III) Sites Evidenced by EPR, IR, NMR, and Luminescence Spectroscopies . Journal of the American Chemical Society, American Chemical Society, 2017, 139 (26), pp.8855-8867. 〈10.1021/jacs.7b02179 〉. 〈hal-01574745〉
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Daniel L. Silverio, Henri A. Van Kalkeren, Ta-Chung Ong, Mathieu Baudin, Maxim Yulikov, et al.. Tailored Polarizing Hybrid Solids with Nitroxide Radicals Localized in Mesostructured Silica Walls. Helvetica Chimica Acta, Wiley, 2017, 100 (6), pp. Article number: e1700101 〈10.1002/hlca.201700101〉. 〈hal-01569653〉
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Sachin R Chaudhari, John M Griffin, Katharina Broch, Anne Lesage, Vincent Lemaur, et al.. Donor-acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy.. Chemical Science, The Royal Society of Chemistry, 2017, 8 (4), pp.3126-3136. 〈10.1039/c7sc00053g〉. 〈hal-01546473〉
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Jayasubba Reddy Yarava, Sachin Rama Chaudhari, Aaron J. Rossini, Anne Lesage, Lyndon Emsley. Solvent suppression in DNP enhanced solid state NMR. Journal of Magnetic Resonance, Elsevier, 2017, 277, pp.149-153. 〈10.1016/j.jmr.2017.02.016〉. 〈hal-01540073〉
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Nick J Brownbill, David Gajan, Anne Lesage, Lyndon Emsley, Frédéric Blanc. Oxygen-17 dynamic nuclear polarisation enhanced solid-state NMR spectroscopy at 18.8 T.. Chemical Communications, Royal Society of Chemistry, 2017, 53 (17), pp.2563-2566. 〈10.1039/c6cc09743j〉. 〈hal-01546471〉
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Wei-Chih Liao, Ta-Chung Ong, David Gajan, Florian Bernada, Claire Sauvée, et al.. Dendritic polarizing agents for DNP SENS.. Chemical Science, The Royal Society of Chemistry, 2017, 8 (1), pp.416-422. 〈10.1039/c6sc03139k〉. 〈hal-01546474〉
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Eva Pump, Jasmine Viger-Gravel, Edy Abou-Hamad, Manoja K Samantaray, Bilel Hamzaoui, et al.. Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy.. Chemical Science, The Royal Society of Chemistry, 2017, 8 (1), pp.284-290. 〈10.1039/c6sc02379g〉. 〈hal-01546475〉
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Pierrick Berruyer, Moreno Lelli, Matthew P. Conley, Daniel L Silverio, M. Widdifield Cory, et al.. Three-Dimensional Structure Determination of Surface Sites. Journal of the American Chemical Society, American Chemical Society, 2017, 139 (2), pp.849-855. 〈10.1021/jacs.6b10894〉. 〈hal-01519030〉
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Wolfram R Grüning, Bieringer Harald, Martin Schwarzwälder, David Gajan, Aurélien Bornet, et al.. Phenylazide Hybrid-Silica – Polarization Platform for Dynamic Nuclear Polarization at Cryogenic Temperatures. Helvetica Chimica Acta, Wiley, 2017, 100 (1), pp. article number: e1600122. 〈10.1002/hlca.201600122〉. 〈hal-01432533〉
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Sachin R. Chaudhari, Dorothea Wisser, Arthur C. Pinon, Pierrick Berruyer, David Gajan, et al.. Dynamic Nuclear Polarization Efficiency Increased by Very Fast Magic Angle Spinning. Journal of the American Chemical Society, American Chemical Society, 2017, 139 (31), pp.10609-10612. 〈10.1021/jacs.7b05194〉. 〈hal-01576023〉
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Jochem Struppe, Caitlin M. Quinn, Manman Lu, Mingzhang Wang, Guangjin Hou, et al.. Expanding the horizons for structural analysis of fully protonated protein assemblies by NMR spectroscopy at MAS frequencies above 100 kHz. Solid State Nuclear Magnetic Resonance, Elsevier, 2017, pp.In Press, Corrected Proof. 〈10.1016/j.ssnmr.2017.07.001〉. 〈hal-01575525〉
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Xiao Ji, Aurélien Bornet, Basile Vuichoud, Jonas Milani, David Gajan, et al.. Transportable hyperpolarized metabolites. Nature Communications, Nature Publishing Group, 2017, 8, pp.13975 〈10.1038/ncomms13975〉. 〈hal-01438968〉
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2016

Journal articles

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Tanya K Todorova, Xavier Rozanska, Christel Gervais, Alexandre Legrand, Linh N Ho, et al.. Molecular Level Characterization of the Structure and Interactions in Peptide-Functionalized Metal-Organic Frameworks.. Chemistry – A European Journal, Wiley-VCH Verlag, 2016, 22 (46), pp.16531-16538. 〈10.1002/chem.201603255〉. 〈hal-01546494〉
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Basile Vuichoud, Estel Canet, Jonas Milani, Aurélien Bornet, David Baudouin, et al.. Hyperpolarization of Frozen Hydrocarbon Gases by Dynamic Nuclear Polarization at 1.2 K. Journal of Physical Chemistry Letters, American Chemical Society, 2016, 7 (16), pp.3235 – 3239. 〈10.1021/acs.jpclett.6b01345〉. 〈hal-01498671〉
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V. D’Anna, S. Norsic, David Gajan, Kevin Sanders, Andrew J. Pell, et al.. Structural Characterization of the EtOH-TiCl 4 -MgCl 2 Ziegler-Natta Precatalyst. Journal of Physical Chemistry C, American Chemical Society, 2016, 120 (32), pp.18075 – 18087. 〈10.1021/acs.jpcc.6b05313〉. 〈hal-01546481〉
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Loren B Andreas, Kristaps Jaudzems, Jan Stanek, Daniela Lalli, Andrea Bertarello, et al.. Structure of fully protonated proteins by proton-detected magic-angle spinning NMR. Proceedings of the National Academy of Sciences of the United States of America , National Academy of Sciences, 2016, 113 (33), pp.9187-9192. 〈10.1073/pnas.1602248113〉. 〈hal-01359815〉
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Patrick Wolf, Maxence Valla, Francisco Nunez-Zarur, Aleix Comas-Vives, Aaron J. Rossini, et al.. Correlating synthetic methods, morphology, atomic-level structure, and catalytic activity of Sn-beta catalysts . ACS Catalysis, American Chemical Society, 2016, 6 (7), pp.4047-4063. 〈10.1021/acscatal.6b00114〉. 〈hal-01355461〉
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Hugh R. W. Dannatt, Michele Felletti, Stefan Jehle, Yao Wang, Lyndon Emsley, et al.. Weak and transient protein interactions determined by solid-state NMR . Angewandte Chemie International Edition, Wiley-VCH Verlag, 2016, 23 (55), pp.6637-6640. 〈10.1002/anie.201511609〉. 〈hal-01355537〉
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Thibault Alphazan, Laurent Mathey, Martin Schwarzwalder, Tsung-Han Lin, Aaron J. Rossini, et al.. Monolayer doping of silicon through grafting a tailored molecular phosphorus precursor onto cxide-passivated silicon surfaces . Chemistry of Materials, American Chemical Society, 2016, 28 (11), pp.3634-3640. 〈10.1021/acs.chemmater.5b04291〉. 〈hal-01355514〉
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Ta-Chung Ong, Wei-Chih Liao, Victor Mougel, David Gajan, Anne Lesage, et al.. Atomistic Description of Reaction Intermediates for Supported Metathesis Catalysts Enabled by DNP SENS.. Angewandte Chemie (English Edition), John Wiley & Sons, 2016, 55 (15), pp.4743-4747. 〈10.1002/anie.201510821〉. 〈hal-01546485〉
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Sachin R Chaudhari, Pierrick Berruyer, David Gajan, Christian Reiter, Frank Engelke, et al.. Dynamic nuclear polarization at 40 kHz magic angle spinning. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (15), pp.10616-10622. 〈10.1039/C6CP00839A 〉. 〈hal-01304650〉
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Matthew P Conley, Giuseppe Lapadula, Kevin Sanders, David Gajan, Anne Lesage, et al.. The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-Supported Organolutetium Complexes from Solid-State NMR Spectroscopy.. Journal of the American Chemical Society, American Chemical Society, 2016, 138 (11), pp.3831-3843. 〈10.1021/jacs.6b00071〉. 〈hal-01546479〉
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Aleix Comas-Vives, Karol Furman, David Gajan, Cen M Akatay, Anne Lesage, et al.. Predictive morphology, stoichiometry and structure of surface species in supported Ru nanoparticles under H-2 and CO atmospheres from combined experimental and DFT studies. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (3), pp.1969-1979. 〈10.1039/c5cp06710c〉. 〈hal-01546478〉
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Rupal Gupta, Manman Lu, Guangjin Hou, Marc A Caporini, Mélanie Rosay, et al.. Dynamic Nuclear Polarization enhanced MAS NMR spectroscopy for structural analysis of HIV-1 protein assemblies. Journal of Physical Chemistry B, American Chemical Society, 2016, 120 (2), pp.329-339. 〈10.1021/acs.jpcb.5b12134〉. 〈hal-01363595〉
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Bilel Hamzaoui, Anissa Bendjeriou-Sedjerari, Eva Pump, Edy Abou-Hamad, Rachid Sougrat, et al.. Atomic-level organization of vicinal acid?base pairs through the chemisorption of aniline and derivatives onto mesoporous SBA15. Chemical Science, The Royal Society of Chemistry, 2016, 7 (9), pp.6099 – 6105. 〈10.1039/c6sc01229a〉. 〈hal-01546482〉
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D Baudouin, Henri A Van Kalkeren, A Bornet, B Vuichoud, L Veyre, et al.. Cubic three-dimensional hybrid silica solids for nuclear hyperpolarization . Chemical Science, The Royal Society of Chemistry, 2016, 7 (11), pp.6846-6850 〈10.1039/c6sc02055k〉. 〈hal-01360905〉
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Dominik Kubicki, Gilles Casano, Martin Schwarzwälder, Sebastien Abel, Claire Sauvée, et al.. Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization. Chemical Science , The Royal Society of Chemistry, 2016, 7 (1), pp.550 – 558. 〈10.1039/C5SC02921J〉. 〈hal-01387080〉
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2015

Journal articles

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Moreno Lelli, Sachin R. Chaudhari, David Gajan, Gilles Casano, Aaron J. Rossini, et al.. Solid-State Dynamic Nuclear Polarization at 9.4 and 18.8 T from 100 K to Room Temperature. Journal of the American Chemical Society, American Chemical Society, 2015, 137 (46), pp.14558-14561. 〈10.1021/jacs.5b08423〉. 〈hal-01414761〉
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Aaron J. Rossini, Judith Schlagnitweit, Anne Lesage, Lyndon Emsley. High-resolution NMR of hydrogen in organic solids by DNP enhanced natural abundance deuterium spectroscopy. Journal of Magnetic Resonance, Elsevier, 2015, 259, pp.192-198. 〈10.1016/j.jmr.2015.08.020〉. 〈hal-01228739〉
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Iuliia Romanenko, David Gajan, Reine Sayah, Delphine Crozet, Erwan Jeanneau, et al.. Iridium(I)/N-Heterocyclic Carbene Hybrid Materials: Surface Stabilization of Low-Valent Iridium Species for High Catalytic Hydrogenation Performance. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 53 (44), pp.12937-12941. 〈10.1002/anie.201505867〉. 〈hal-01228564〉
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Maxence Valla, Aaron J. Rossini, Maxime Caillot, Céline Chizallet, Pascal Raybaud, et al.. Atomic description of the interface between silica and alumina in aluminosilicates through Dynamic Nuclear Polarization Surface-Enhanced NMR spectroscopy and first-principles calculations. Journal of the American Chemical Society, American Chemical Society, 2015, 137 (33), pp.10710-10719. 〈10.1021/jacs.5b06134〉. 〈hal-01229899〉
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Rahul Sangodkar, Benjamin Smith, David Gajan, Aaron J. Rossini, Lawrence Roberts, et al.. Influences of Dilute Organic Adsorbates on the Hydration of Low-Surface-Area Silicates. Journal of the American Chemical Society, American Chemical Society, 2015, 137 (25), pp.8096-8112. 〈10.1021/jacs.5b00622〉. 〈hal-01186949〉
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Maria Baias, Anne Lesage, Sonia Aguado, Jérôme Canivet, Virginie Moizan-Baslé, et al.. Superstructure of a Substituted Zeolitic Imidazolate Metal–Organic Framework Determined by Combining Proton Solid-State NMR Spectroscopy and DFT Calculations. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 54 (20), pp.5971–5976. 〈10.1002/anie.201500518〉. 〈hal-01158452〉
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2014

Journal articles

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Dominik Kubicki, Aaron J Rossini, Armin Purea, Alexandre Zagdoun, Olivier Ouari, et al.. Amplifying Dynamic Nuclear Polarization of frozen solutions by incorporating dielectric particles. Journal of the American Chemical Society, American Chemical Society, 2014, 136 (44), pp.5711-15718. 〈10.1021/ja5088453〉. 〈hal-01230280〉
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David Gajan, Aurélien Bornet, Basile Vuichoud, Jonas Milani, Roberto Melzi, et al.. Hybrid polarizing solids for pure hyperpolarized liquids through dissolution dynamic nuclear polarization.. Proceedings of the National Academy of Sciences of the United States of America , National Academy of Sciences, 2014, 111 (41), pp.14693-14697. 〈10.1073/pnas.1407730111〉. 〈hal-01070302〉
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Emeline Barbet-Massin, Andrew J. Pell, Joren S. Retel, Loren B Andreas, Kristaps Jaudzems, et al.. Rapid Proton-Detected NMR Assignment for Proteins with Fast Magic Angle Spinning. Journal of the American Chemical Society, American Chemical Society, 2014, 136 (35), pp.12489-12497. 〈10.1021/ja507382j〉. 〈hal-01070782〉
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Patrick Wolf, Maxence Valla, Aaron J. Rossini, Aleix Comas-Vives, Francisco Nunez-Zarur, et al.. NMR signatures of the active sites in Sn-beta zeolite. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2014, 53 (38), pp.10179-10183. 〈10.1002/anie.201403905〉. 〈hal-01230430〉
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Matthew P Conley, Aaron J. Rossini, Aleix Comas-Vives, Maxence Valla, Gilles Casano, et al.. Silica-surface reorganization during organotin grafting evidenced by Sn-119 DNP SENS: a tandem reaction of gem-silanols and strained siloxane bridges. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2014, 16 (33), pp.17822-17827. 〈10.1039/c4cp01973c〉. 〈hal-01070828〉
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Y. Jayasubba Reddy, Vipin Agarwal, Anne Lesage, Lyndon Emsley, Kv Ramanathan. Heteronuclear proton double quantum-carbon single quantum scalar correlation in solids. Journal of Magnetic Resonance, Elsevier, 2014, 245, pp.31-37. 〈10.1016/j.jmr.2014.05.004〉. 〈hal-01070845〉
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Emeline Barbet-Massin, Michele Felletti, Robert Schneider, Stefan Jehle, Guillaume Communie, et al.. Insights into the Structure and Dynamics of Measles Virus Nucleocapsids by (1)H-detected Solid-state NMR.. Biophysical Journal, Biophysical Society, 2014, 107 (4), pp.941-946. 〈10.1016/j.bpj.2014.05.048〉. 〈hal-01070838〉
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Loredana Protesescu, Aaron J. Rossini, Dominik Kriegner, Maxence Valla, Antoine De Kergommeaux, et al.. Unraveling the core-shell structure of ligand-capped Sn/SnOx nanoparticles by surface-enhanced nuclear magnetic resonance, Mössbauer, and X-ray absorption spectroscopies.. ACS Nano, American Chemical Society, 2014, 8 (3), pp.2639-2648. 〈10.1021/nn406344n〉. 〈hal-01071626〉
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Aaron J. Rossini, M. Widdifield Cory, Alexandre Zagdoun, Moreno Lelli, Martin Schwarzwalder, et al.. DNP enhanced NMR spectroscopy for pharmaceutical formulations. Journal of the American Chemical Society, American Chemical Society, 2014, 136 (6), pp.2324-2334. 〈10.1021/ja4092038〉. 〈hal-00977912〉
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Moreno Lelli, Aaron J. Rossini, Gilles Casano, Olivier Ouari, Paul Tordo, et al.. Hydrophobic radicals embedded in neutral surfactants for dynamic nuclear polarization of aqueous environments at 9.4 Tesla. Chemical Communications, Royal Society of Chemistry, 2014, 50 (71), pp.10198-10201. 〈10.1039/c4cc02152e〉. 〈hal-01070850〉
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2013

Journal articles

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Matthew P Conley, Victor Mougel, Dmitry V Peryshkov, William P Forrest, David Gajan, et al.. A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst.. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (51), pp.19068-19070. 〈10.1021/ja410052u〉. 〈hal-00942164〉
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David Gajan, Martin Schwarzwälder, Matthew P Conley, Wolfram R Grüning, Aaron J. Rossini, et al.. Solid-phase polarization matrixes for dynamic nuclear polarization from homogeneously distributed radicals in mesostructured hybrid silica materials.. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (41), pp.15459-15466. 〈10.1021/ja405822h〉. 〈hal-00977918〉
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Matthew P Conley, Ruben M Drost, Mathieu Baffert, David Gajan, Cornelis Elsevier, et al.. A Well-Defined Pd Hybrid Material for the Z-Selective Semihydrogenation of Alkynes Characterized at the Molecular Level by DNP SENS.. Chemistry – A European Journal, Wiley-VCH Verlag, 2013, 19 (37), pp.12234-12238. 〈10.1002/chem.201302484〉. 〈hal-00864651〉
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Aaron J. Rossini, Alexandre Zagdoun, Moreno Lelli, Anne Lesage, Christophe Copéret, et al.. Dynamic nuclear polarization surface enhanced NMR spectroscopy. Accounts of Chemical Research, American Chemical Society, 2013, 46 (9), pp.1942-1951. 〈10.1021/ar300322x〉. 〈hal-00954530〉
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Emeline Barbet-Massin, Andrew J. Pell, Michael J. Knight, Amy L. Webber, Isabella C Felli, et al.. 13C-detected through-bond correlation experiments for protein resonance assignment by ultra-fast MAS solid-state NMR.. ChemPhysChem, Wiley-VCH Verlag, 2013, 14 (13), pp.3131-3137. 〈10.1002/cphc.201201097〉. 〈hal-00915846〉
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Emeline Barbet-Massin, Andrew J. Pell, Kristaps Jaudzems, Trent W. Franks, Joren S. Retel, et al.. Out-and-back C-13-C-13 scalar transfers in protein resonance assignment by proton-detected solid-state NMR under ultra-fast MAS. Journal of Biomolecular NMR, Springer Verlag, 2013, 56 (4), pp.379-386. 〈10.1007/s10858-013-9757-3〉. 〈hal-00864674〉
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Alexandre Zagdoun, Gilles Casano, Olivier Ouari, Martin Schwaerzwalder, Aaron J. Rossini, et al.. Large molecular weight nitroxide biradicals providing efficient dynamic nuclear polarization at temperatures up to 200 K. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (34), pp.12790-12797. 〈10.1021/ja405813t〉. 〈hal-00867717〉
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James W. Emsley, Moreno Lelli, Anne Lesage, Geoffrey R. Luckhurst. A comparison of the conformational distributions of the achiral symmetric liquid crystal dimer CB7CB in the achiral nematic and chiral twist-bend nematic phases. Journal of Physical Chemistry B, American Chemical Society, 2013, 117 (21), pp.6547-6557. 〈10.1021/jp4001219〉. 〈hal-00850457〉
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Manorja K Samantaray, Johan Alauzun, David Gajan, Santosh Kavitake, Ahmad Mehdi, et al.. Evidence for Metal−Surface Interactions and Their Role in Stabilizing Well-Defined Immobilized Ru−NHC Alkene Metathesis Catalysts. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (8), pp.3193-3199. 〈10.1021/ja311722k〉. 〈hal-00802998〉
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Etienne Grau, Anne Lesage, Sébastien Norsic, Christophe Copéret, Vincent Monteil, et al.. Tetrahydrofuran in TiCl4/THF/MgCl2: a Non-Innocent Ligand for Supported Ziegler-Natta Polymerization Catalysts. ACS Catalysis, American Chemical Society, 2013, 3 (1), pp.52-56. 〈10.1021/cs300764h〉. 〈hal-00799544〉
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Alexandre Zagdoun, Aaron J. Rossini, Matthew P. Conley, Wolfram R. Gruening, Martin Schwarzwaelder, et al.. Improved Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy through Controlled Incorporation of Deuterated Functional Groups. Angewandte Chemie, Wiley-VCH Verlag, 2013, 52 (4), pp.1222-1225. 〈10.1002/anie.201208699〉. 〈hal-00799493〉
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Miao Sun, Edy Abou-Hamad, Aaron J. Rossini, Jizhe Zhang, Anne Lesage, et al.. Methane Reacts with Heteropolyacids Chemisorbed on Silica to Produce Acetic Acid under Soft Conditions. Journal of the American Chemical Society, American Chemical Society, 2013, 135 (2), pp.804-810. 〈10.1021/ja309966j〉. 〈hal-00799220〉
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Pilar Garcia-Garcia, Alexandre Zagdoun, Christophe Copéret, Anne Lesage, Urbano Diaz, et al.. In Situ Preparation of a Multifunctional Chiral Hybrid Organic-Inorganic Catalyst for Asymmetric Multicomponent Reactions. Chemical Science , The Royal Society of Chemistry, 2013, 4 (5), pp.2006-2012. 〈10.1039/c3sc22310h〉. 〈hal-00977717〉
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Maria Baias, M. Widdifield Cory, Jean-Nicolas Dumez, Hugh P. G. Thompson, Timothy G. Cooper, et al.. Powder crystallography of pharmaceutical materials by combined crystal structure prediction and solid-state H-1 NMR spectroscopy. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2013, 15 (21), pp.8069-8080. 〈10.1039/c3cp41095a〉. 〈hal-00860775〉
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Wolfram R. Gruening, Aaron J. Rossini, Alexandre Zagdoun, David Gajan, Anne Lesage, et al.. Molecular-level characterization of the structure and the surface chemistry of periodic mesoporous organosilicates using DNP-surface enhanced NMR spectroscopy. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2013, 15 (32), pp.13270-13274. 〈10.1039/c3cp00026e〉. 〈hal-00859918〉
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2012

Journal articles

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Aaron J. Rossini, Alexandre Zagdoun, Franziska Hegner, Martin Schwarzwalder, David Gajan, et al.. Dynamic Nuclear Polarization NMR Spectroscopy of Microcrystalline Solids. Journal of the American Chemical Society, American Chemical Society, 2012, 134 (40), pp.16899-16908. 〈10.1021/ja308135r〉. 〈hal-00799569〉
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Laetitia Beguin, James W. Emsley, Moreno Lelli, Anne Lesage, Geoffrey R. Luckhurst, et al.. The Chirality of a Twist-Bend Nematic Phase Identified by NMR Spectroscopy. Journal of Physical Chemistry B, American Chemical Society, 2012, 116 (27), pp.7940-7951. 〈10.1021/jp302705n〉. 〈hal-00799658〉
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Amy L. Webber, Andrew J. Pell, Emeline Barbet-Massin, Michael J. Knight, Ivano Bertini, et al.. Combination of DQ and ZQ Coherences for Sensitive Through-Bond NMR Correlation Experiments in Biosolids under Ultra-Fast MAS. ChemPhysChem, Wiley-VCH Verlag, 2012, 13 (9), pp.2405-2411. 〈10.1002/cphc.201200099〉. 〈hal-00799692〉
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Rachel Nathaniel Kerber, Anthony Kermagoret, Emmanuel Callens, Pierre Florian, Dominique Massiot, et al.. Nature and Structure of Aluminum Surface Sites Grafted on Silica from a Combination of High-Field Aluminum-27 Solid-State NMR Spectroscopy and First-Principles Calculations. Journal of the American Chemical Society, American Chemical Society, 2012, 134 (15), pp.6767-6775. 〈10.1021/ja3008566〉. 〈hal-00699535〉
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Alexandre Zagdoun, Gilles Casano, Olivier Ouari, Giuseppe Lapadula, Aaron J. Rossini, et al.. A Slowly Relaxing Rigid Biradical for Efficient Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy: Expeditious Characterization of Functional Group Manipulation in Hybrid Materials. Journal of the American Chemical Society, American Chemical Society, 2012, 134 (4), pp.Volume: 134 Issue: 4 Pages: 2284-2291 DOI:. 〈10.1021/ja210177v〉. 〈hal-00699587〉
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Aaron J. Rossini, Alexandre Zagdoun, Moreno Lelli, Jérôme Canivet, Sonia Aguado, et al.. Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2012, 51 (1), pp.123-127. 〈10.1002/anie.201106030〉. 〈hal-00699781〉
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G. De Luca, Lyndon Emsley, Anne Lesage, D. Merlet. The structures and conformations of mesogenic molecules in the pre-transitional region of the isotropic phase: 5OCB and MBBA and their mixtures. Liquid Crystals, Taylor & Francis, 2012, 39 (2), pp.211-219. 〈10.1080/02678292.2011.631043〉. 〈hal-00977881〉
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Aaron J. Rossini, Alexandre Zagdoun, Moreno Lelli, David Gajan, Fernando Rascon, et al.. One hundred fold overall sensitivity enhancements for Silicon-29 NMR spectroscopy of surfaces by dynamic nuclear polarization with CPMG acquisition. Chemical Science , The Royal Society of Chemistry, 2012, 3 (1), pp.108-115. 〈10.1039/c1sc00550b〉. 〈hal-00699857〉
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Alessandro Marchetti, Stefan Jehle, Michèle Felletti, Michael J. Knight, Yao Wang, et al.. Backbone assignment of fully protonated solid proteins by 1H detection and ultrafast magic-angle-spinning NMR spectroscopy. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2012, 51 (43), pp.10756-10759. 〈10.1002/anie.201203124〉. 〈hal-00809214〉
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Veronika Vitzthum, Pascal Miéville, Diego Carnevale, Marc A. Caporini, David Gajan, et al.. Dynamic nuclear polarization of quadrupolar nuclei using cross polarization from protons: surface-enhanced aluminium-27 NMR. Chemical Communications, Royal Society of Chemistry, 2012, 48 (14), pp.1988-1990. 〈10.1039/c2cc15905h〉. 〈hal-00699814〉
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Alexandre Zagdoun, Aaron J. Rossini, David Gajan, Adrien Bourdolle, Olivier Ouari, et al.. Non-aqueous solvents for DNP surface enhanced NMR spectroscopy. Chemical Communications, Royal Society of Chemistry, 2012, 48 (5), pp.654-656. 〈10.1039/c1cc15242d〉. 〈hal-00699834〉
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2011

Journal articles

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Moreno Lelli, David Gajan, Anne Lesage, Marc A. Caporini, Veronika Vitzthum, et al.. Fast characterization of functionalized silica materials by silicon-29 surface-enhanced NMR spectroscopy using dynamic nuclear polarization. Journal of the American Chemical Society, American Chemical Society, 2011, 133 (7), pp.2104-2107. 〈10.1021/ja110791d〉. 〈hal-00809355〉
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David Gajan, Daniel Levine, Eva Zocher, Christophe Copéret, Anne Lesage, et al.. Probing surface site heterogeneity through 1D and INADEQUATE P-31 solid state NMR spectroscopy of silica supported PMe3-Au(I) adducts. Chemical Science , The Royal Society of Chemistry, 2011, 2 (5), pp.928-931. 〈10.1039/c0sc00579g〉. 〈hal-00809034〉
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Ivano Bertini, Lyndon Emsley, Isabella C. Felli, Ségolène Laage, Anne Lesage, et al.. High-resolution and sensitivity through-bond correlations in ultra-fast magic angle spinning (MAS) solid-state NMR. Chemical Science , The Royal Society of Chemistry, 2011, 2 (2), pp.345-348. 〈10.1039/c0sc00397b〉. 〈hal-00809106〉
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Michael J. Knight, Amy L. Webber, Andrew J. Pell, Paul Guerry, Emeline Barbet-Massin, et al.. Fast resonance assignment and fold determination of human superoxide dismutase by high-resolution proton-detected solid-state MAS NMR spectroscopy. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2011, 50 (49), pp.11697-11701. 〈10.1002/anie.201106340〉. 〈hal-00809132〉
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Arthur Roussey, David Gajan, Tarun K. Maishal, Anhurada Mukerjee, Laurent Veyre, et al.. A highly ordered mesostructured material containing regularly distributed phenols: preparation and characterization at a molecular level through ultra-fast magic angle spinning proton NMR spectroscopy. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2011, 13 (10), pp.4230-4233. 〈10.1039/c0cp02137g〉. 〈hal-00809086〉
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